Naruto Episode 39: Bushy Brow`s Jealousy: Lions Barrage Unleashed!
Episode 39 of 220 of Naruto, aired July 2, 2003, 25 minutes. Available with English subtitles and dub where released.
Episode summary
Unable to use his chakra against Akado, Sasuke has to rely on good old-fashioned taijutsu to defeat him. Kakashi senses something is wrong with Sasuke and takes him away after the match.