Bleach Episode 134: The Beautiful Patissier, Yumichika!
Episode 134 of 366 of Bleach, aired July 18, 2007, 24 minutes. Available with English subtitles and dub where released.
Episode summary
Hanatarō of 4th Squad and Rin of the Technological Development Bureau are sent to the real world on a investigation of the Arrancar. They meet a cake chef who requests their help to fulfill his last wish. Things become complicated however, when a Menos Grande appears to crash the party.