Bleach Episode 139: Ichigo vs Grimmjow, 11 Seconds Battle!
Episode 139 of 366 of Bleach, aired September 5, 2007, 24 minutes. Available with English subtitles and dub where released.
Episode summary
Ichigo continues his battle with Grimmjow, with his hollow mask, that is only going to last about 11 seconds. He has the upper hand too, until his mask breaks. Meanwhile, Hitsugaya is fighting Yammy, well Luppi is fighting Yumichika. Luppi gets bored and wants to fight all four and releases, beats Hitsugaya and fights Ikkaku, Matsumoto, and Yumichika at once, as things start to look bad Urahara comes in and saves them. Ulquiorra appears before Orihime and tells him that they she needs to come with him right now or her friends will be killed.