Bleach Episode 77: Unquellable Hatred! The Shinigami that Kenpachi Cut Down
Episode 77 of 366 of Bleach, aired April 11, 2006, 25 minutes. Available with English subtitles and dub where released.
Episode summary
Ichigo seems to be having trouble fighting Ichinose when Jin steps in and offers for Ichigo join them since he likes his spirit. Then Ichinose remembers when Zaraki defeated his captain and how he met Jin.