Bleach Episode 96: Ichigo Byakuya Kariya, Battle of the Three Extremes!
Episode 96 of 366 of Bleach, aired September 12, 2006, 25 minutes. Available with English subtitles and dub where released.
Episode summary
Ichigo, Byakuya and Kariya contiune there battle. As they battle they are interupted by by Ran'tao. Koga comes and saves Kariya. Byakuya leaves to hunt him down. Ishida finds the battle ground, and then Ran'tao takes Ichigo and Ishida to explain about the Bount.